Product ID:DK BLUE WATER-BAKE 816, W1871
MSDS Date:08/25/1988
FSC:8010
NIIN:00N012165
MSDS Number: BQNZY

EASTERN CHEM-LAC

1100 EASTERN AVENUE
MALDEN, MA 02148
US

Emergency Phone: 617-322-8000

Info Phone: 617-322-8000

Cage: 62792

EASTERN CHEM-LAC CORP

MALDEN, MA 02148-6129 US

Telephone: 617-322-8000

Cage: 62792

FORMALDEHYDE.ACGIH TLV FROM INTENDED CHANGE LIST 1991.

CAS: 50-00-0

RTECS: LP8925000

Fraction By Weight: <0.1%

OSHA PEL SEE 1910.1048

ACGIH TLV: C 0.3 PPM; A2; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

2-BUTOXYETHANOL (ETHYLENE GLYCOL MONOBUTYL ETHER)

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: 5-10%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 25 PPM; 9293

DIMETHYLETHANOLAMINE (DMEA).LD50 RAT ORAL 2.03 ML/KG.

CAS: 108-01-0

RTECS: KK6125000

Fraction By Weight: <5%

OSHA PEL N/K

ACGIH TLV: N/K

DIGLYCOL ETHER (DIETHYLENE GLYCOL MONOBUTYL ETHER)

CAS: 112-34-5

RTECS: KJ9100000

Fraction By Weight: <5%

OSHA PEL N/K

ACGIH TLV: N/K

CAUSING DIZZINESS, HEADACHES OR NAUSEA

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

POSSIBLE LOSS OF CONSIOUSNESS. MAY CAUSE NOSE AND

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ANIMAL STUDIES HAVE CLEARLY
DEMONSTRATED ADVERSE EFFECTS ON THE CNS, THE HEMATOPOIETIC TISSUE,
BLOOD, KIDNEYS, AND LIVER, ASSOCIATED W/ADMINISTRATION OF ETHYLENE
GLYCOL MONOBUTYL ETHER (EGBE) AND ETHY LENE GLYCOL MONOBUTYL ETHER
ACETATE (EGBEA). (EXTRACTED FROM DHHS (NIOSH) PUB NO. 90-118). (SEE
OTHER PRECAUTIONS)
Explanation of Carcinogenicity:FORMALDEHYDE (<0.1%):LTD EVID FOR CARC
IN HUM/SUFF EVID FOR CARC IN ANIM (IARC,1987).SUSP HUM CARC/KNOWN
ANIM (SEE SUPP)
Effects of Overexposure:EYES:BUTOXYETHANOL-IRRITANT. SKIN:
BUTOXYETHANOL-PENETRATES SKIN READILY. CAN BE ABSORBED.
DMEA-EXTREMELY IRRITATING. INGEST:DMEA-CORROSIVE. ASPIRATION INTO
LUNGS CAN CAUSE CHEMICAL PNEUMONIA. BUTOXYE THANOL-MODERATELY
TOXIC. INHAL:DMEA-POSSIBLE ASTHMA & FIBROTIC DISEASE. MAY AFFECT
BRAIN/NERVOUS SYSTEM (SEE INGRED 5)
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:IMMED FLUSH WITH CLEAN WATER FOR AT LEAST 15
MIN,OCCASNLY LIFTING LIDS.GET IMMEDIATE ATTN.SKIN:IMMED REMOVE
CONTAMINATED CLOTHING.WASH AFFECTED AREAS W/ SOAP & WATER.IF
STICKY,USE WATERLESS CLEAN ER FIRST.INGESTION:ADMINISTER WARM WATER
AND GET MED ATTN IMMED.DO NOT INDUCE VOMITING.INHALATION:IMMED MOVE
TO FRESH AIR.GIVE OXYGEN OR ARTF RESP AS NEEDED.GET MED ATTN
IMMED.PROMPT ACTION IS ESSNTL.

Flash Point:NONE
Lower Limits:NONE
Upper Limits:N/K
Extinguishing Media:ALCOHOL FOAM,DRY CHEMICAL,CARBON DIOXIDE,WATER FOG,
CLASS B FIRE EXTINGUISHER.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .USE WATER TO COOL FIRE EXPOSED CONTAINERS.
NOTIFY AUTH IF LIQ ENTERS SEWERS/PUBLIC WATERS.
Unusual Fire/Explosion Hazard:VAPORS OFTEN HEAVIER THAN AIR,MAY TRAVEL
ALONG GROUND.KEEP CNTNR CLSD TIGHT.ISOLATE FROM HEAT,SPARKS,OPEN
FLAME.MAY EXPLODE IF EXPOS TO EXTREME HEAT.(SEE SUPP)

Spill Release Procedures:REMOVE ALL IGNITION SOURCES. KEEP PEOPLE AWAY.
RECOVER FREE LIQUID AND SPREAD ABSORBENT IN SPILL AREA. VENTILATE
AREA. OPEN ALL WINDOWS AND DOORS.
Neutralizing Agent:N/K

Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED. KEEP
AWAY FROM SPARKS & OPEN FLAMES. USE ADEQUATE VENT. DO NOT CUT/WELD.
AVOID PRLNGD/RPTD BREATHING OR SKIN CONTACT.
Other Precautions:DO NOT INCINERATE CNTNRS."EMPTY CONTAINERS" ARE HAZ
UNLESS THOROUGHLY CLEANED. HLTH HAZ:PRLNG/RPTD SOLVENT OVEREXPOS IS
ASSOCD W/PERM BRAIN & NERV SYS DMG. 2-BUTOXYETHANOL MAY CAUSE
HEMOLYSIS & LIVER & KIDNEY INJURY.DMEA: POSS PULM DISEASE.

Respiratory Protection:IN CONFINED AREAS USE MSHA APPROVED MASK WITH
CHEMICAL CANISTER OR SUPPLIED AIR.
Ventilation:USE EXPLOSION PROOF VENTILATOR TO KEEP VAPOR BELOW 100 PPM.
Protective Gloves:INSOLUBLE RUBBER OR PLASTIC.
Eye Protection:CHEM WORKERS GOGS.MAY ADD FULL (SEE SUP)
Other Protective Equipment:PROTECTIVE FOOTWEAR AND APRON.
Work Hygienic Practices:CLEAN CONTAMINATED CLOTHING THOROUGHLY BEFORE
REUSE.
Supplemental Safety and Health
BP:134-446F,56.67-230C.LIQ DENS:>1,H2O=1. EXPLO HAZ:CONSIDER EMPTY
CNTNRS HAZ UNLESS THORO CLEANED.HAZ DECOMP PROD: CO.EXPLAN OF
CARCIN:CARC (NTP,1989).ACGIH A2=SUSP HUM CARC (1991).KNOWN HUM CARC
(OS HA,1985).KNOWN TO CAUSE CANCER (CAL PROP 65,1988).EYE
PROT:LENGTH FSHLD TO GOGS .ENTRY RTE:INH/SKIN/INGEST

HCC:C2
Boiling Pt:B.P. Text:SEE SUPP
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:>1,AIR=1
Spec Gravity:1.18,WATER=1
Evaporation Rate & Reference:SLOWER THAN BUTYL ACETATE
Solubility in Water:N/K
Appearance and Odor:BLUE LIQUID WITH AROMATIC ODOR.
Percent Volatiles by Volume:37.8

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH OXIDANTS SUCH AS CHLORINE.
Stability Condition to Avoid:HIGH TEMPERATURES OR OPEN FLAMES.
Hazardous Decomposition Products:CARBON MONOXIDE MAY FORM WHEN BURNED.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS . TREAT AS HAZARDOUS WASTE. DO NOT
INCINERATE CONTAINERS.

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